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Heptafluoroisopropyl diazomethane (i-C3F7CHN2): in situ generation and synthesis of pyrazoles

Org. Biomol. Chem.
2017, 15 (35), 7243-7478

DOI: 10.1039/c7ob01579h

Mykhailiuk P. K.
A novel chemical reagent – heptafluoroisopropyl diazomethane (i-C3F7CHN2) – has been generated in situ in aqueous media. It readily reacts with electron-deficient alkynes towards polyfluorinated pyrazoles that are important in agrochemistry.

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