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Arylation of perfluoroalkyl vinyl sulfoxides via the Heck reaction

Tetrahedron Lett. 2015, 56 (10), 1259-1262

DOI: 10.1016/j.tetlet.2015.01.136

Sokolenko L. V.; Yagupolskii Y. L.; Vlasenko Y. G.; Babichenko L. N.; Lipetskij V. O.; Anselmi E.; Magnier E.

Heck reactions of perfluoroalkyl vinyl sulfoxides with aryl iodides are studied and palladium(II) acetate is shown to be the most convenient catalyst for this process. New E-1-aryl-2-perfluoroalkylsulfinylethylenes are synthesized. In all cases, by-products without a perfluoroalkylsulfinyl group are formed.

Arylation of perfluoroalkyl vinyl sulfoxides via the Heck reaction

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