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New Life for Diazoacetonitrile (N2CHCN): in situ Generation and Practical Synthesis of CN-Pyrazoles

Eur. J. Org. Chem. 2015, 33, 7235-7239

DOI: 10.1002/ejoc.201501027

Mykhailiuk P. K.

Explosive diazoacetonitrile (N2CHCN) was generated in situ and used in the practical synthesis of agrochemistry-related CN-pyrazoles. In situ generated N2CHCN is much safer than the individual reagent. The developed method is, therefore, expected to make this reagent as useful in chemistry as ethyl diazoacetate (N2CHCO2Et).

New Life for Diazoacetonitrile (N2CHCN): in situ Generation and Practical Synthesis of CN-Pyrazoles

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