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Org Biomol Chem 2025, 23 (26), 6343-6348

DOI: 10.1039/d5ob00691k

Shuvakin S.; Serhieiev O.; Dashko M.; Pendiukh V.; Ivonin S.; Shishkina S. et al.

A scalable, diastereoselective protocol for synthesizing scarce 2-substituted cyclopropanols is presented. Our previous protocol for vinyl boron pinacolates cyclopropanation is adapted for flow conditions. This work establishes a fundamental understanding of both the stability of cyclopropanols under the formation conditions and the impact of the nature of the substituents on that stability.

 

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