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J. Org. Chem. 2023, 88 (1), 1-17

DOI: 10.1021/acs.joc.2c02262

Kornii Y.; Shablykin O.; Tarasiuk T.; Stepaniuk O.; Matvienko V.; Aloshyn D.; Zahorodniuk N.; Sadkova I.; Mykhailiuk P.

The previously unknown difluoromethyl diazirines and the previously neglected trifluoromethyl-aliphatic diazirines were synthesized and characterized. Model photolabeling experiments and biological studies showed that these compounds could indeed be used as photoaffinity labels.

 

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