Arylation of perfluoroalkyl vinyl sulfoxides via the Heck reaction
Tetrahedron Lett. 2015, 56 (10), 1259-1262
DOI: 10.1016/j.tetlet.2015.01.136
Sokolenko L. V.; Yagupolskii Y. L.; Vlasenko Y. G.; Babichenko L. N.; Lipetskij V. O.; Anselmi E.; Magnier E.
Heck reactions of perfluoroalkyl vinyl sulfoxides with aryl iodides are studied and palladium(II) acetate is shown to be the most convenient catalyst for this process. New E-1-aryl-2-perfluoroalkylsulfinylethylenes are synthesized. In all cases, by-products without a perfluoroalkylsulfinyl group are formed.
