Correction: When SF5 outplays CF3: effects of pentafluorosulfanyl decorated scorpionates on copper
Chem Sci 2024, 15 (3), 1159-1161
DOI: 10.1039/d3sc90243a
Noonikara-Poyil A.; Munoz-Castro A.; Boretskyi A.; Mykhailiuk P.; Dias H.
The authors regret that in the original version of the manuscript, an inadvertent error was made during percent buried volume calculation and topographical steric map creation of bis(pyrazolyl)borate supporting ligands of [Ph2B(3‑(SF5)Pz)2]Cu(C2H4), [Ph2B(3‑(CF3)Pz)2]Cu(C2H4), [Ph2B(3‑(SF5)Pz)2]Cu(CO) and [Ph2B(3‑(CF3)Pz)2]Cu(CO) using SambVca. This was caused due to the removal of only ethylene and CO groups, rather than the entire Cu–ethylene or Cu–CO moiety (including the metal atom) as suggested by SambVca protocol. Correct percent buried volumes (%Vbur) pertinent to the results and discussion section are given below.
