Synthesis of fluorinated dipyrazolyl sulfones from bis(2-fluoro-2-polyfluoroalkylalkenyl) sulfones and diazomethane
Chem. Heterocycl. Compd. 2019, 55 (11), 1065-1069
DOI: 10.1007/s10593-019-02578-3
Borodkin Y.; Rusanov E.; Khizhan A.; Shermolovich Y.
The reactions of diazomethane with bis(2-fluoro-2-polyfluoroalkylalkenyl) sulfones are accompanied by dehydrofluorination and lead to the formation of new dipyrazolyl sulfones containing polyfluoroalkyl substituents at position 4 of the pyrazole ring. The structure of four new sulfones was confirmed by X-ray diffraction analysis.
