CAS 81549-07-7, Cat. No EN300-7358500
Electrophilic aminating reagent for Grignard reagents
Acetoxime O-(2,4,6-trimethylphenylsulfonate is a reliable reagent for electrophilic aminating reaction of Grignard reagents. It is a stable solid soluble in ether, THF, and partial in benzene. The use of Copper(I) Iodide or MgCl2 as a catalyst in the amination of aryl Grignard reagents decreases the reaction time remarkably and/or increases the yield1.
Synonyms: (propan-2-ylideneamino) 2,4,6-trimethylbenzenesulfonate; 2-propanone; O-[(2,4,6-trimethylphenyl)sulfonyl]oxime
Selected publication
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Acetoxime O-(2,4,6-Trimethylphenyl) Sulfonate.
Erdik E. Encyclopedia of Reagents for Organic Synthesis 2001. DOI: 10.1002/047084289X.ra019