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Synthesis , 2010, 10, 1633-1638

DOI: 10.1055/s-0029-1218712

Khodakovskiy P. V.; Mykhailiuk P. K.; Volochnyuk D. M.; Tolmachev A. A.

2-Trifluoroacetyl-1,3-benzothiazole reacts with anilines to form the corresponding trifluoromethyl-substituted alcohols. The reaction regioselectivity (ortho/para) was shown to depend strongly on the structure of the aniline. meta-Substituted anilines tend to form the corresponding ortho-substituted products, in contrary to the previous literature data.

Noncatalytic Electrophilic Oxyalkylation of Anilines with 2-Trifluoroacetyl-1,3-benzothiazole

Khodakovskiy P. V.; Mykhailiuk P. K.; Volochnyuk D. M.; Tolmachev A. A.
Synthesis 2010, 10, 1633-1638
DOI: 10.1055/s-0029-1218712

 

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