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Acta Cryst. E 2022, 78 (12), 1156-1160

DOI: 10.1107/s2056989022010362

Vynohradov O. S.; Davydenko Y. M.; Pavlenko V. A.; Naumova D. D.; Shova S.; Petlovanyi D.

The title compound, [NiCl2(C4H6N2)4]·2CH3CN, is a mononuclear octa­hedral NiII pyrazole-based complex. Two aceto­nitrile mol­ecules are linked to the NiII complex by N—H⋯N hydrogen bonds. The NiII atom is octa­hedrally coordinated by four N atoms of four 4-methyl-1H-pyrazole ligands, forming the equatorial plane. The axial positions are occupied by two Cl atoms. [NiCl2(C4H6N2)4]·2CH3CN was synthesized by the reaction of 4-methyl-1H-pyrazole with nickel(II) chloride hexa­hydrate in aceto­nitrile solution under ambient conditions and characterized by single-crystal X-ray diffraction analysis. A Hirshfeld surface analysis was performed, which suggests that the most important contributions to the surface contacts are from H⋯H (62.1%), H⋯N/N⋯H (13.7%), H⋯C/C⋯H (13.4%) and H⋯Cl/Cl⋯H (10.1%) inter­actions.

 

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