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Synthesis of [1,2]dithiolo[3,4-b]pyridines via the reaction of dithiomalondianilide with arylmethylidenemalononitriles

Chem. Heterocycl. Compd. 2015, 51 (4), 389‑392

DOI: 10.1007/s10593-015-1713-6

Dotsenko V.; Krivokolysko S.; Frolov K.; Chigorina E.; Polovinko V.; Dmitrienko A.; Bushmarinov I.

6-Amino-4-aryl-7-phenyl-3-(phenylamino)-4,7-dihydro-3Н-[1,2]dithiolo[3,4-b]pyridine-5-carbonitriles were synthesized via the reaction of arylmethylidenemalononitriles with dithiomalonic acid dianilide in the presence of an excess of morpholine. The structure of 6-amino-4-(3,4-dimethoxyphenyl)-7-phenyl-3-(phenylamino)-4,7-dihydro-3Н-[1,2]dithiolo[3,4-b]pyridine-5-carbonitrile was studied by X-ray structural analysis.

Synthesis of [1,2]dithiolo[3,4-b]pyridines via the reaction of dithiomalondianilide with arylmethylidenemalononitriles

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