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Eur. J. Org. Chem. 2020, 2020 (22), 3261-3269

DOI: 10.1002/ejoc.202000314

Blahun O.; Melnychenko H.; Kuchkovska Y.; Zhersh S.; Tolmachev A.; Grygorenko O.

Two approaches to synthesis of functionalized bridged bicyclic sulfonamides with a bridgehead Nitrogen atom were developed. The target compounds were obtained either by introduction of a CH2SO2 bridge into functionalized monocyclic substrates or by final‐step carboxylation of parent bicyclic cores. The described methods allowed preparation of the final products on a multigram scale.

 

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