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Methyl 2-[[(diphenylmethylene)amino]oxy]-2-oxoacetate

CAS 2694872-01-8, Cat. No EN300-39868153
Reagent for photochemical aminocarboxylation

Methyl 2-[[(diphenylmethylene)amino]oxy]-2-oxoacetate
EN300-39868153

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The reagent provides a straightforward synthetic route for the synthesis of a wide range of β-amino acid derivatives1. The reaction employs a metal-free, photochemically-induced, highly regioselective intermolecular aminocarboxylation of alkenes or (hetero)arenes. This mild method is notable for its broad substrate scope and excellent tolerance of sensitive functional groups.

Synonyms: (diphenylmethylidene)amino methyl oxalate

Selected publication

  1. Photochemical Single-Step Synthesis of β-Amino Acid Derivatives from Alkenes and (Hetero)Arenes.

    Tan G.; Das M.; Keum H.; Bellotti P.; Daniliuc C.; Glorius F. Nat Chem 2022, 14 (10), 1174–1184. DOI: 10.1038/s41557-022-01008-w

 

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