Stannanes for coupling reactions

Suzuki reaction has become one of the most powerful synthetic tools in organic chemistry to construct the C(sp2)-C(sp2) bond. Unfortunately, many boronic acids bearing the electron-deficient heterocyclic substituents do not exist. Stannanes are more stable and can also undergo coupling reaction catalyzed with transition metals.

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Properties

  • readily prepared, purified and stored
  • compatible with a wide range of functional groups
  • mild reaction conditions
  • not sensitive to moisture in Stille coupling

Reactivity

Stille reaction runs selectively in the presence of the active chlorine atoms.

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>100 Stannanes in gram amounts in stock. Custom synthesis of further analogues and compound libraries

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